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无机化学(第3版/影印版)(Inorganic chemistry)
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无机化学(第3版/影印版)(Inorganic chemistry)

  • 作者:(美)米斯勒(Miessler G.L.) (美)塔尔(Tarr D.A.)
  • 出版社:高等教育出版社
  • ISBN:9787040155860
  • 出版日期:2007年11月01日
  • 页数:706
  • 定价:¥52.00
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    内容提要
    共16章,主要包括无机化学介绍、原子结构、价键理论简介、对称性与群论、分子轨道、酸碱理论、晶体、主族元素、异构体、价键、原子光谱、反应及其机理、有机金属化学、有机金属反应及其机理、主族与有机金属的关联。每章节后有习题,书后有习题解析。并附录常用热力学数据表等内容。
    目录
    PREFACE
    1 INTRODUCTION TO INORGANIC CHEMISTRY
    1-1 What is Inorganic Chemistry?
    1-2 Contrasts with Organic Chemistry
    1-3 Genesis of the Elements (The Big Bang)and Flrmation of the Earth
    1-4 Nuclear Reactions and Radioactivity
    1-5 Distribution of Elements on Earth
    1-6 The History of Inorganic Chemistry
    2 ATOMIC STRUCTURE
    2-1 Historical Development of Atomic Theory
    2-1-1 The Periodic Table
    2-1-2 Discover of Subatomic Particles and the Bohr Atom
    2-2 The Schrodinger Equation
    2-2-1 The Particle in a Box
    2-2-2 Quantum Numbers and Atomic Wave Functions
    2-2-3 The Aufbau Principle
    2-2-4 Shielding
    2-3 Perildic Properties of Atoms
    2-3-1 Ionization Energy
    2-3-2 Elecrton Affinity
    2-3-3 Covalent and Ionic Radii
    3 SIMPLE BONDING THEORY
    3-1 Liewis Electron-Dot Diagrams
    3-1-1 Resonance
    3-1-2 Expanded shells
    3-1-3 Formal Charge
    3-1-4 Multiple Bonds in Be and B Compounds
    3-2 Valence Shell Electron Pair Repulsion Theory
    3-2-1 Lone Pair Repulsion
    3-2-2 Multiple Bonds
    3-2-3 Electroneatuvity and Atomic Size Effects
    3-2-4 Ligand Close-Packing
    3-3 Polar Molecules
    3-4 Hydrogen Bonding
    4 SYMMETRY AND GROUP THEORY
    4-1 Symmetry Element and Operations
    4-2 Point Groups
    4-2-1 Groups of Low and High Symmetry
    4-2-2 Other Groups
    4-3 Properties and Representations of Groups
    4-3-1 Matrices
    4-3-2 Representations of Point Groups
    4-3-3 Character Tables
    4-4 Examples and Applications of Symmetry
    4-4-1 Chirality
    4-4-2 Molecular Vibrations
    5 MOLECULAR ORBITALS
    5-1 Formation of Molecular Orbiatls form Atomic Orbitals
    5-1-1 Molecular Orbitals form s Orbitals
    5-1-2 Molecular Orbitals form p Orbitals
    5-1-3 Molecular Orbitals form d Orbitals
    5-1-4 Nonbonding Orbitals and Other Factors
    5-2 Homonuclear Diatomic Molecules
    5-2-1 Molecular Orbitals
    5-2-2 Orbitals Mixing
    5-2-3 First and Second Row Mocecules
    5-2-4 Photoelectron Spectroscopy
    5-2-5 Correlation Diagrams
    5-3 Heteronuclear Diatomic Molecules
    5-3-1 Polar Bonds
    5-3-2 Ionic Compounds and Molecular Orbiatals
    5-4 Molecular Orbitals for Larger Molecules
    5-4-1 FHF
    5-4-2 CO2
    5-4-3 H2O
    5-4-4 NH3
    5-4-5 BF3
    5-4-6 Molecular shapes
    5-4-7 Hybrid Orbitals
    5-5 Expanded Shells and Molecular Orbitals
    6 ACID-BASE AND DONOR-ACCEPTOR CHEMISTRY
    6-1 Acid-Base Concepts as Organizing Concepts
    6-1-1 History
    6-2 Major Acid-Base Concepts
    6-2-1 Arrhenius Concept
    6-2-2 Brnsted-Lowry Concept
    6-2-3 Solvent System Concept
    6-2-4 Lewis Concept
    6-2-5 Frontier Orbitals and Acid-Base Reactions
    6-2-6 Hydrogen Bonding
    6-2-7 Electronic Spectra(Including Charge Transfer)
    ……
    7 THE CRYSTALLINE SOLID STATE
    8 CHEMISTRY OF THE MAIN GROUP ELEMENTS
    9 COORDINATION CHEMISTRYⅠ:STRUSTURES AND ISOMERS
    10 COORDINATION CHEMISTRYⅡ:BONDING
    11 COORDINATION CHEMISTRYⅢ:ELECTRONIC SPECTRA
    12 COORDINATION CHEMISTRYⅣ:REACTIONS AND MECHANISMS
    13 ORGANOMETALLIC CHEMISTRY
    14 ORGANOMETALLIC REACTONS AND CATALYSIS
    15 PARALLELS BETWEEN MAIN GROUP AND ORGANOMETALLIC CHEMISTRY
    16 BIOINORGANIC AND ENVIRONMENTAL CHEMISTRY
    APPENDIXA ANSWERA TO EXERCISES
    APPENDIXA B-1 IONIC RADII
    APPENDIXA B-2 IONIZATION ENERGY
    APPENDIXA B-3 ELECTORON AFFINITY
    APPENDIXA B-4 ELECTRONEGATIVITY
    APPENDIXA B-5 ABSOLUTE HARDNESS PARAMETERS
    APPENDIXA B-6 CA,EA,CB,AND EB VALUES
    APPENDIXA B-7 LATIMER DIAGRAMS FOR SELECTED ELEMENTS
    APPENDIXA C CHARACTER TABLES
    APPENDIXA ELECTRON-DOT DIAGRAMS AND FORMAL CHARGE
    INDEX

    与描述相符

    100

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